Actually, you need to use Collectors.toMap here instead of Collectors.groupingBy:
Map<String, Valuta> map =
getValute().stream()
.collect(Collectors.toMap(Valuta::getCodice, Function.identity()));
groupingBy is used to group elements of a Stream based on a grouping function. 2 Stream elements that will have the same result with the grouping function will be collected into a List by default.
toMap will collect the elements into a Map where the key is the result of applying a given key mapper and the value is the result of applying a value mapper. Note that toMap, by default, will throw an exception if a duplicate is encountered.