The easiest answer is probably to change your working directory, then call the second .py file from where it is:
python a.py && cd testA && python ../b.py
Of course you might find it even easier to write a script that does it all for you, like so:
Save this as runTests.sh in the same directory as a.py is:
#!/bin/sh
python a.py
cd testA
python ../b.py
Make it executable:
chmod +x ./runTests.sh
Then you can simply enter your directory and run it:
./runTests.sh