the SynchronousQueue is more of a handoff, whereas the LinkedBlockingQueue just allows a single element. The difference being that the put() call to a SynchronousQueue will not return until there is a corresponding take() call, but with a LinkedBlockingQueue of size 1, the put() call (to an empty queue) will return immediately.
I can’t say that i have ever used the SynchronousQueue directly myself, but it is the default BlockingQueue used for the Executors.newCachedThreadPool() methods. It’s essentially the BlockingQueue implementation for when you don’t really want a queue (you don’t want to maintain any pending data).