Raise an error manually in T-SQL to jump to BEGIN CATCH block

you can use raiserror. Read more details here

–from MSDN

BEGIN TRY
    -- RAISERROR with severity 11-19 will cause execution to 
    -- jump to the CATCH block.
    RAISERROR ('Error raised in TRY block.', -- Message text.
               16, -- Severity.
               1 -- State.
               );
END TRY
BEGIN CATCH
    DECLARE @ErrorMessage NVARCHAR(4000);
    DECLARE @ErrorSeverity INT;
    DECLARE @ErrorState INT;

    SELECT 
        @ErrorMessage = ERROR_MESSAGE(),
        @ErrorSeverity = ERROR_SEVERITY(),
        @ErrorState = ERROR_STATE();

    -- Use RAISERROR inside the CATCH block to return error
    -- information about the original error that caused
    -- execution to jump to the CATCH block.
    RAISERROR (@ErrorMessage, -- Message text.
               @ErrorSeverity, -- Severity.
               @ErrorState -- State.
               );
END CATCH;

EDIT
If you are using SQL Server 2012+ you can use throw clause. Here are the details.