For your second example, you already gave the explanation yourself—Queue is a module, which cannot be called.
For the third example: I assume that you use Queue.Queue together with multiprocessing. A Queue.Queue will not be shared between processes. If the Queue.Queue is declared before the processes then each process will receive a copy of it which is then independent of every other process. Items placed in the Queue.Queue by the parent before starting the children will be available to each child. Items placed in the Queue.Queue by the parent after starting the child will only be available to the parent. Queue.Queue is made for data interchange between different threads inside the same process (using the threading module). The multiprocessing queues are for data interchange between different Python processes. While the API looks similar (it’s designed to be that way), the underlying mechanisms are fundamentally different.
multiprocessingqueues exchange data by pickling (serializing) objects and sending them through pipes.Queue.Queueuses a data structure that is shared between threads and locks/mutexes for correct behaviour.