As pointed out by Blckknght, you and Stanislav Ivanov in the comments, you can use NamedTuple:

from typing import NamedTuple


class NameInfo(NamedTuple):
    name: str
    first_letter: str


def get_info(name: str) -> NameInfo:
    return NameInfo(name=name, first_letter=name[0])

Starting from Python 3.8 you can use TypedDict which is more similar to what you want:

from typing import TypedDict


class NameInfo(TypedDict):
    name: str
    first_letter: str


def get_info(name: str) -> NameInfo:
    return {'name': name, 'first_letter': name[0]}