Pixel data is ARGB, 1 byte for alpha, 1 for red, 1 for green, 1 for blue. Alpha is the most significant byte, blue is the least significant. On a little-endian machine, like yours and many others, the little end is stored first so the byte order is bb gg rr aa. So 0 0 255 255 equals blue = 0, green = 0, red = 255, alpha = 255. That’s red.
This endian-ness order detail disappears when you cast bd.Scan0 to an int* (pointer-to-integer) since integers are stored little-endian as well.