Pandas – add value at specific iloc into new dataframe column

There are two steps to created & populate a new column using only a row number…
(in this approach iloc is not used)

First, get the row index value by using the row number

rowIndex = df.index[someRowNumber]

Then, use row index with the loc function to reference the specific row and add the new column / value

df.loc[rowIndex, 'New Column Title'] = "some value"

These two steps can be combine into one line as follows

df.loc[df.index[someRowNumber], 'New Column Title'] = "some value"