Make WPF Application Fullscreen (Cover startmenu)

You’re probably missing the WindowState="Maximized", try the following:

<Window x:Class="HTA.MainWindow"
    xmlns="http://schemas.microsoft.com/winfx/2006/xaml/presentation"
    xmlns:x="http://schemas.microsoft.com/winfx/2006/xaml"
    Title="MainWindow" Height="350" Width="525"
    WindowStyle="None" ResizeMode="NoResize"  
    WindowStartupLocation="CenterScreen" WindowState="Maximized">