listOfData.stream()
.flatMap(e -> e.entrySet().stream())
.collect(Collectors.groupingBy(Map.Entry::getKey,
Collectors.mapping(Map.Entry::getValue,
Collectors.toList())));
update:
Slightly different variant to user1692342‘s answer for completeness.
list.stream()
.map(e -> Arrays.asList(e.get("Role"), e.get("Name")))
.collect(Collectors.groupingBy(e -> e.get(0),
Collectors.mapping(e -> e.get(1), Collectors.toList())));