Iterate through dictionary values?

Depending on your version:

Python 2.x:

for key, val in PIX0.iteritems():
    NUM = input("Which standard has a resolution of {!r}?".format(val))
    if NUM == key:
        print ("Nice Job!")
        count = count + 1
    else:
        print("I'm sorry but thats wrong. The correct answer was: {!r}.".format(key))

Python 3.x:

for key, val in PIX0.items():
    NUM = input("Which standard has a resolution of {!r}?".format(val))
    if NUM == key:
        print ("Nice Job!")
        count = count + 1
    else:
        print("I'm sorry but thats wrong. The correct answer was: {!r}.".format(key))

You should also get in the habit of using the new string formatting syntax ({} instead of % operator) from PEP 3101:

https://www.python.org/dev/peps/pep-3101/