char firstLetter = someString.charAt(0);
String oneLetter = String.valueOf(someChar);
You find the documentation by identifying the classes likely to be involved. Here, candidates are java.lang.String and java.lang.Character.
You should start by familiarizing yourself with:
- Primitive wrappers in
java.lang - Java Collection framework in
java.util
It also helps to get introduced to the API more slowly through tutorials.
- Manipulating characters in a String