If, like me, you’re faced with some wonky 3rd party web service that will only accept form content, you can work around the problem like this:
// Let's assume you've got your key-value pairs organised into a nice Dictionary<string, string> called formData
var encodedItems = formData.Select(i => WebUtility.UrlEncode(i.Key) + "=" + WebUtility.UrlEncode(i.Value));
var encodedContent = new StringContent(String.Join("&", encodedItems), null, "application/x-www-form-urlencoded");
// Post away!
var response = await client.PostAsync(url, encodedContent);