Or if in Linux, try:
# To save to an absolute path.
r = requests.get(url)
with open('/path/I/want/to/save/file/to/file_name.pdf', 'wb') as f:
f.write(r.content)
# To save to a relative path.
r = requests.get(url)
with open('folder1/folder2/file_name.pdf', 'wb') as f:
f.write(r.content)
See open() function docs for more details.