You can write it out fairly straight-forward, using os.listdir and the os.path functions:
import os
basedir="C:/Test"
for fn in os.listdir(basedir):
if not os.path.isdir(os.path.join(basedir, fn)):
continue # Not a directory
if ',' in fn:
continue # Already in the correct form
if ' ' not in fn:
continue # Invalid format
firstname,_,surname = fn.rpartition(' ')
os.rename(os.path.join(basedir, fn),
os.path.join(basedir, surname + ', ' + firstname))