You can use the Align widget to position your FloatingActionButton‘s in the Stack.
Stack(
children: <Widget>[
Align(
alignment: Alignment.bottomLeft,
child: FloatingActionButton(...),
),
Align(
alignment: Alignment.bottomRight,
child: FloatingActionButton(...),
),
],
)
One button uses constant Alignment.bottomLeft for its alignment property and the other one respectively Alignment.bottomRight.