You cannot alter the target list (i in this case) of a for loop. Use a while loop instead:
while i < 10:
i += 1
if i == 2:
i += 3
Alternatively, use an iterable and increment that:
from itertools import islice
numbers = iter(range(10))
for i in numbers:
if i == 2:
next(islice(numbers, 3, 3), None) # consume 3
By assigning the result of iter() to a local variable, we can advance the loop sequence inside the loop using standard iteration tools (next(), or here, a shortened version of the itertools consume recipe). for normally calls iter() for us when looping over a iterator.