PEP 3131 — Supporting Non-ASCII Identifiers says
All identifiers are converted into the normal form NFKC while parsing; comparison of identifiers is based on NFKC.
You can use unicodedata to test the conversions:
import unicodedata
unicodedata.normalize('NFKC', '𝑓')
# f
which would indicate that '𝑓' gets converted to 'f' in parsing. Leading to the expected:
𝑓 = "Some String"
print(f)
# "Some String"