This functionality can be achieved with a call to the flatMap method on the stream, which takes a Function that maps the Stream item to another Stream on which you can collect.
Here, the flatMap method converts the Stream<Collection<Long>> to a Stream<Long>, and collect collects them into a Collection<Long>.
Collection<Long> longs = streamOfCollections
.flatMap( coll -> coll.stream())
.collect(Collectors.toList());