You can only use yield return in a function that returns an IEnumerable or an IEnumerator, not a List<T>.
You need to change your function to return an IEnumerable<DesktopComputer>.
Alternatively, you can rewrite the function to use List<T>.ConvertAll:
return GetComputerIdTags().ConvertAll(pcTag =>
new DesktopComputer() {
AssetTag = pcTag,
Description = "PC " + pcTag,
AcquireDate = DateTime.Now
});