Your header field should look like this:
Header : Authorization
Value : Basic base64('YourOrgName:YourAPIKEY');
You can get the base64 value of your string here:
https://www.base64encode.org/
For example, for my-org-name:123key4api it should be bXktb3JnLW5hbWU6MTIza2V5NGFwaQ==.
The complete header would look like:
Authorization: Basic bXktb3JnLW5hbWU6MTIza2V5NGFwaQ==