OrderBy is just an alias for the sort function.
From the Spark documentation:
/**
* Returns a new Dataset sorted by the given expressions.
* This is an alias of the `sort` function.
*
* @group typedrel
* @since 2.0.0
*/
@scala.annotation.varargs
def orderBy(sortCol: String, sortCols: String*): Dataset[T] = sort(sortCol, sortCols : _*)