If you want to log in with the user that is now logged in on the Facebook app and you still have a token valid for a previous user, you can detect the error and log out in your FacebookCallback like this:
@Override
public void onError(FacebookException e) {
if (e instanceof FacebookAuthorizationException) {
if (AccessToken.getCurrentAccessToken() != null) {
LoginManager.getInstance().logOut();
}
}
}
Then you can log in again using the LoginManager.