Specifying “all odd values” in crontab?

Depending on your version of cron, you should be able to do (for hours, say):

   1-23/2

Going by the EXTENSIONS section in the crontab(5) manpage:

   Ranges can include "steps", so "1-9/2" is the same as "1,3,5,7,9".

For a more portable solution, I suspect you just have to use the simple list:

   1,3,5,7,9,11,13,15,17,19,21,23

But it might be easier to wrap your command in a shell script that will immediately exit if it’s not called in an odd minute.