Try withColumn with the function when as follows:
val sqlContext = new SQLContext(sc)
import sqlContext.implicits._ // for `toDF` and $""
import org.apache.spark.sql.functions._ // for `when`
val df = sc.parallelize(Seq((4, "blah", 2), (2, "", 3), (56, "foo", 3), (100, null, 5)))
.toDF("A", "B", "C")
val newDf = df.withColumn("D", when($"B".isNull or $"B" === "", 0).otherwise(1))
newDf.show() shows
+---+----+---+---+
| A| B| C| D|
+---+----+---+---+
| 4|blah| 2| 1|
| 2| | 3| 0|
| 56| foo| 3| 1|
|100|null| 5| 0|
+---+----+---+---+
I added the (100, null, 5) row for testing the isNull case.
I tried this code with Spark 1.6.0 but as commented in the code of when, it works on the versions after 1.4.0.