Postgres Alter Column Integer to Boolean

Try this:

ALTER TABLE mytabe ALTER COLUMN mycolumn DROP DEFAULT;
ALTER TABLE mytabe ALTER mycolumn TYPE bool USING CASE WHEN mycolumn=0 THEN FALSE ELSE TRUE END;
ALTER TABLE mytabe ALTER COLUMN mycolumn SET DEFAULT FALSE;

You need to remove the constraint first (as its not a boolean), and secondly your CASE statement was syntactically wrong.