The tab character is \t. Notice the use of " instead of '.
$chunk = "<html>\t<head>\t\t<title>\t</head>";
PHP Strings – Double quoted
If the string is enclosed in double-quotes (“), PHP will interpret
more escape sequences for special characters:…
\t horizontal tab (HT or 0x09 (9) in ASCII)
Also, let me recommend the fputcsv() function which is for the purpose of writing CSV files.