Check the value of the PHP_OS constantDocs.
It will give you various values on Windows like WIN32, WINNT or Windows.
See as well: Possible Values For: PHP_OS and php_unameDocs:
if (strtoupper(substr(PHP_OS, 0, 3)) === 'WIN') {
echo 'This is a server using Windows!';
} else {
echo 'This is a server not using Windows!';
}