Passing multiple argument through CommandArgument of Button in Asp.net

You can pass semicolon separated values as command argument and then split the string and use it.

<asp:TemplateField ShowHeader="false">
    <ItemTemplate>
       <asp:LinkButton ID="lnkCustomize" Text="Customize"  CommandName="Customize"  CommandArgument="<%#Eval("IdTemplate") + ";" +Eval("EntityId")%>"  runat="server"> 
       </asp:LinkButton>   
    </ItemTemplate>   
</asp:TemplateField>

at server side

protected void gridview_RowCommand(object sender, GridViewCommandEventArgs e)
{
      string[] arg = new string[2];
      arg = e.CommandArgument.ToString().Split(';');
      Session["IdTemplate"] = arg[0];
      Session["IdEntity"] = arg[1];
      Response.Redirect("Samplepage.aspx");
}