Sorry, not possible. Dict literals and dict comprehensions map to the built-in dict type, in a way that’s hardcoded at the C level. That can’t be overridden.
You can use this as an alternative, though:
OrderedDict((i, i * i) for i in range(3))
Addendum: as of Python 3.6, all Python dictionaries are ordered. As of 3.7, it’s even part of the language spec. If you’re using those versions of Python, no need for OrderedDict: the dict comprehension will Just Work (TM).