In the Dev Tools, open Settings, then Devices, add a custom device with any name and user agent equal to Googlebot/2.1.
Finally, in Device Mode, at the left of the top bar, choose the device (the default is Responsive).
You can test the captcha in https://www.google.com/recaptcha/api2/demo?invisible=true
(This is a demo of the Invisible Recaptcha. You can remove the url invisible parameter to test with the captcha button)