Try specifying the “file://” at the start of the URL.
// Also, use the absolute path of the file:
webbrowser.open('file://' + os.path.realpath(filename))
Or
import webbrowser
new = 2 # open in a new tab, if possible
// open a public URL, in this case, the webbrowser docs
url = "http://docs.python.org/library/webbrowser.html"
webbrowser.open(url,new=new)
// open an HTML file on my own (Windows) computer
url = "file://d/testdata.html"
webbrowser.open(url,new=new)