For that you may use the color_discrete_sequence
argument.
fig = px.scatter(df, x="sepal_width", y="sepal_length", color_discrete_sequence=['red'])
This argument is to use a custom color paletter for discrete color
factors, but if you are not using any factor for color
it will use the first element for all the points in the plot.
More about discrete color palletes: https://plotly.com/python/discrete-color/