It depends on which Ruby version you use:
Ruby 2.4 and higher:
It just works, as since Ruby v2.4.0 supports Unicode case mapping:
"мария".capitalize #=> Мария
Ruby 2.3 and lower:
"maria".capitalize #=> "Maria"
"мария".capitalize #=> мария
The problem is, it just doesn’t do what you want it to, it outputs мария instead of Мария.
If you’re using Rails there’s an easy workaround:
"мария".mb_chars.capitalize.to_s # requires ActiveSupport::Multibyte
Otherwise, you’ll have to install the unicode gem and use it like this:
require 'unicode'
Unicode::capitalize("мария") #=> Мария
Ruby 1.8:
Be sure to use the coding magic comment:
#!/usr/bin/env ruby
puts "мария".capitalize
gives invalid multibyte char (US-ASCII), while:
#!/usr/bin/env ruby
#coding: utf-8
puts "мария".capitalize
works without errors, but also see the “Ruby 2.3 and lower” section for real capitalization.