You can take advantage of the bootstraps .btn.active class and just add it to the button you wish toggled first and you can use jQuerys toggleClass to untoggle the buttons. Demo.
Just noticed that twitter has a button script that you can call for this effect, here is a fixed demo with the results you were expecting.
After looking at what you actually wanted from the comment i updated my fiddle with the results you’re looking for.
I added a function that pulls the current day using javascripts getDay method from an array and toggles the corresponding day on the button group by targetting the id of the button: demo
Relevant Code:
JS
function today() {
var arr = ["0", "1", "2", "3", "4", "5", "6"]; //first day of the week is sunday and its index is 0
var currentDay = new Date().getDay();
return (arr[currentDay]);
}
var day = '[id="test' + today() +'"]'; // we take the current day from the array and add the beginning of the class name and save it in a variable
$(day).button('toggle');