How can I pass POST parameters in a URL?

You could use a form styled as a link. No JavaScript is required:

<form action="/do/stuff.php" method="post">
    <input type="hidden" name="user_id" value="123" />
    <button>Go to user 123</button>
</form>

CSS:

button {
    border: 0;
    padding: 0;
    display: inline;
    background: none;
    text-decoration: underline;
    color: blue;
}
button:hover {
    cursor: pointer;
}

See: http://jsfiddle.net/SkQRN/