If you just want to make sure that the alias doesn’t exist, just unalias it and redirect its error to /dev/null like this:
unalias foo 2>/dev/null
You can check if an alias is set with something like this:
alias foo >/dev/null 2>&1 && echo "foo is set as an alias" || echo "foo is not an alias"
As stated in the manpage:
For each name in the argument list for which no value is sup-
plied, the name and value of the alias is printed. Alias
returns true unless a name is given for which no alias has been
defined.