Go template: can’t evaluate field X in type Y (X not part of Y but stuck in a {{range}} loop)

The contents of dot (.) are assigned to $ after invocation of range, so you can use $ to access lang (on play):

{{ range .users }}
  <form action="/{{ $.lang }}/users" method="POST">
    <input type="text" name="Username" value="{{ .Username }}">
    <input type="text" name="Email" value="{{ .Email }}">
  </form>
{{ end }}

The behavior is documented here:

When execution begins, $ is set to the data argument passed to Execute, that is, to the starting value of dot.

If you are using nested ranges, you can always fall back to assign dot to something else using the with statement or variable assignment statements. See the other answer for that.