Using indexOf is an enormous waste of resources. The right way is initializing a variable with index’s value, like this:
<ng-container matColumnDef="position">
<th mat-header-cell *matHeaderCellDef mat-sort-header> Num. </th>
<td mat-cell *matCellDef="let element; let i = index">{{i + 1}}</td>
</ng-container>
https://material.angular.io/components/table/examples
UPDATE:
If you are using pagination the index can be calculated this way:
<ng-container matColumnDef="position">
<th mat-header-cell *matHeaderCellDef mat-sort-header> Num. </th>
<td mat-cell *matCellDef="let i = index">
{{this.paginator.pageIndex == 0 ? i + 1 : 1 + i + this.paginator.pageIndex * this.paginator.pageSize}}
</td>
</ng-container>