To find the sessions, as a DBA use
select sid,serial# from v$session where username="<your_schema>"
If you want to be sure only to get the sessions that use SQL Developer, you can add and program = 'SQL Developer'. If you only want to kill sessions belonging to a specific developer, you can add a restriction on os_user
Then kill them with
alter system kill session '<sid>,<serial#>'(e.g.
alter system kill session '39,1232')
A query that produces ready-built kill-statements could be
select 'alter system kill session ''' || sid || ',' || serial# || ''';' from v$session where username="<your_schema>"
This will return one kill statement per session for that user – something like:
alter system kill session '375,64855';
alter system kill session '346,53146';