You can’t render geometry (Pixi.Rectangle), they are meant for calculations only. You can do the following instead:
var graphics = new PIXI.Graphics();
graphics.beginFill(0xFFFF00);
// set the line style to have a width of 5 and set the color to red
graphics.lineStyle(5, 0xFF0000);
// draw a rectangle
graphics.drawRect(0, 0, 300, 200);
stage.addChild(graphics);
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