I assume you can work your way out on using postgresql utilities.
Create the clusters
$ initdb -D /path/to/datadb1
$ initdb -D /path/to/datadb2
Run the instances
$ pg_ctl -D /path/to/datadb1 -o "-p 5433" -l /path/to/logdb1 start
$ pg_ctl -D /path/to/datadb2 -o "-p 5434" -l /path/to/logdb2 start
Test streaming
Now you have two instances running on ports 5433 and 5434. Configuration files for them are in data dirs specified by initdb. Tweak them for streaming replication.
Your default installation remains untouched in port 5432.