You do something along these lines
if( CMAKE_SIZEOF_VOID_P EQUAL 8 )
set( BOOST_LIBRARY "/boost/win64/lib" )
else( CMAKE_SIZEOF_VOID_P EQUAL 8 )
set( BOOST_LIBRARY "/boost/win32/lib" )
endif( CMAKE_SIZEOF_VOID_P EQUAL 8 )
set( CMAKE_EXE_LINKER_FLAGS ${BOOST_LIBRARY} )