Can I get an item from a PriorityQueue without removing it yet?

If a is a PriorityQueue object, You can use a.queue[0] to get the next item:

from queue import PriorityQueue

a = PriorityQueue()

a.put((10, "a"))
a.put((4, "b"))
a.put((3,"c"))

print(a.queue[0])
print(a.queue)
print(a.get())
print(a.queue)
print(a.get())
print(a.queue)

output is :

(3, 'c')
[(3, 'c'), (10, 'a'), (4, 'b')]
(3, 'c')
[(4, 'b'), (10, 'a')]
(4, 'b')
[(10, 'a')]

but be careful about multi thread access.