Go uses method sets to declare which methods belong to a type. There is only one way to declare functions with receiver types (methods):
func (v T) methodName(...) ... { }
Since nested functions are forbidden, there is no way to define a method set on anonymous structs.
The second thing that will not allow this is that methods are read-only. Method values were introduced to allow to pass methods around and use them in goroutines but not to manipulate the method set.
What you can do instead is to provide a ProtoThing and refer to underlying implementations of your anonymous struct (on play):
type ProtoThing struct {
itemMethod func() float64
setItemMethod func(float64)
}
func (t ProtoThing) Item() float64 { return t.itemMethod() }
func (t ProtoThing) SetItem(x float64) { t.setItemMethod(x) }
// ...
t := struct { ProtoThing }{}
t.itemMethod = func() float64 { return 2.0 }
t.setItemMethod = func(x float64) { item = x }
This works because by embedding ProtoThing the method set is inherited. Thus the anonymous struct also satisfies the Thing interface.