If your equation does not fit on a single line, then the multline
(note that that’s multline without an “i”, not “multiline”) environment probably is what you need:
\begin{multline}
first part of the equation \\
= second part of the equation
\end{multline}
If you also need some alignment respect to the first part, you can use split
:
\begin{equation}
\begin{split}
first part &= second part #1 \\
&= second part #2
\end{split}
\end{equation}
Both environments require the amsmath
package.
See also aligned
as pointed out in an answer below.