It won’t bother the compiler. The compiler will (or should anyway) give you a diagnostic when/if you use it on code that doesn’t fit the requirements of a constexpr.
At the same time, I’d be a bit hesitant to just slap it on there because you could. Even though it doesn’t/won’t bother the compiler, your primary audience is other people reading the code. At least IMO, you should use constexpr to convey a fairly specific meaning to them, and just slapping it on other expressions because you can will be misleading. I think it would be fair for a reader to wonder what was going on with a function that’s marked as a constexpr, but only used as a normal run-time function.
At the same time, if you have a function that you honestly expect to use at compile time, and you just haven’t used it that way yet, marking it as constexpr might make considerably more sense.