Windows can’t find the file on subprocess.call()

When the command is a shell built-in, add a shell=True to the call.

E.g. for dir you would type:

import subprocess
subprocess.call('dir', shell=True)

To quote from the documentation:

The only time you need to specify shell=True on Windows is when the command you wish to execute is built into the shell (e.g. dir or copy). You do not need shell=True to run a batch file or console-based executable.