Json.NET has SelectToken. It uses a syntax similar to DataBinder.Eval to get JSON via a string expression:
JObject o = JObject.Parse("{'People':[{'Name':'Jeff'},{'Name':'Joe'}]}");
// get name token of first person and convert to a string
string name = (string)o.SelectToken("People[0].Name");
Or if you wanted to select multiple values:
JObject o = JObject.Parse("{'People':[{'Name':'Jeff','Roles':['Manager', 'Admin']}]}");
// get role array token of first person and convert to a list of strings
IList<string> names = (string)o.SelectToken("People[0].Roles").Select(t => (string)t).ToList();
Documentation: Querying JSON with SelectToken