Unless you have a specific requirement to work with XML 1.1 (which is very rare), you should read the XML 1.0 Recommendation.
Tim Bray, one of the original editors of the specification, has created an excellent annotated version of it which you can find at http://www.xml.com/axml/axml.html
For a bit more info/opinion on XML 1.1, check out what Elliotte Rusty Harold has to say here:
http://www.ibiblio.org/xml/books/effectivexml/chapters/03.html
Summary:
Everything you need to know about XML 1.1 can be summed up in two rules:
- Don’t use it.
- (For experts only) If you speak Mongolian, Yi, Cambodian, Amharic, Dhivehi, Burmese or a very few other languages and you want to write your markup (not your text but your markup) in these languages, then you can set the version attribute of the XML declaration to 1.1. Otherwise, refer to rule 1.